Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
DHW Demand
DHW Selector in Maximum (+) position
CH Selector in Minimum (-) position
ON/OFF Switch in ON position
Set Multimeter to DC Volts Set meter to measure DC Volts
Disconnect plug from gas valve and make safe
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the voltage between the blue (pin 9) and red (pin 18) on the connector marked X20.
During the sparking stage of the ignition sequence a voltage between approximately 16V and 24V DC should be measured.
Note:
The appliance will try to ignite 5 times before going to lockout and the voltage will only be present when the appliance is attempting ignition.