Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Disconnect the lead from the flame sense electrode

Measurement:

Measure the resistance of the flame sense electrode.
Expect short circuit / zero resistance.
Also visually inspect the electrode for signs of damage,
cracked ceramic insulation, good general condition and
that it is correctly positioned above the burner.