Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Gain access to PCB (use Insulation Mat as required)
Remove connector X20 from the PCB

Measurement:

Measure for resistance across pins 7 & 5 (red leads) of connector X20.
The resistance will vary according to the boiler temperature but should conform approximately to the table below: