Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Gain access to PCB (use Insulation Mat as required)
Ensure No demands
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow the boiler to complete its self-check.
Ensure boiler is not attempting to ignite.
Measure for A/C voltage across the unused terminal (spark generator) and a suitable earth connection.
Expected voltage approximately 131 Vac.
Note.
Ensure a good connection is made or misdiagnosis will occur.