Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Disconnect the low voltage Molex connector from the PCB

Measurement:

Measure resistance across the red wires of the connector.
Note:
Boiler will go to overheat lockout if the thermistor resistance goes below approx. 700 Ohms.