Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Gain access to PCB (use Insulation Mat as required)
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset boiler as required.
Measure the voltage to earth at the yellow wire of the 6 way plug towards the rear of the PCB. This is the power supply from the PCB to the pump.
Expect mains voltage.