Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Selector Switch to Hot Water and Heating
Gain access to PCB (use insulation mat as necessary)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the voltage across the live brown (4) and neutral blue (3) leads at connector marked X3 on the PCB.
Expect mains voltage.
Replace the cover after test.