Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Boiler On/Off Switch On
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow fan to run and ignition sequence to commence.
Measure the voltage at connector CN1 third from bottom (red wire) on control PCB and a suitable neutral.
Once the burner has lit voltage should increase from approximately 0V AC to mains voltage.