Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Apply heating demand, allow fan to start and burner to establish.
Remove CH demand (turn boiler stat to Off) check for voltage across red and black connections on the gas valve as the appliance shuts down.
Warning: 200V DC may be present.