Set Appliance State:

Mains Power Off
Set Boiler Control Thermostat to MAX position
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Ensure external controls are calling for heat
Use insulation mat as required
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the voltage between the N/C terminal on the air pressure switch (orange wire) and the neutral (N) connection (blue wire) at the mains input terminal block.
Mains voltage expected.