Set Appliance State:

Set Multimeter to AC Voltage Set meter to measure AC Volts
CH Demand
Isolate Mains Power to appliance as per TOPs P4
Gain access to boiler terminal block
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the Voltage across the room thermostat terminal marked ON (connection 6) and the neutral marked N (Blue wire, connection 1) on the main connector block.
Note:
If a Room Thermostat/External Controls are not fitted there will be a Link Wire connected to the connection marked ON and the connection marked HW.