Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Unplug electrode from HT lead
Remove electrode from heat exchanger

Observation:

Thoroughly check the electrode and lead for signs of damage, cracked ceramic insulation, continuity and good general condition.
Refit electrode after test.
Also check the electrode is straight and the correct distance from the burner, if in doubt measure the gap as shown. It should be 7-9mm