Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Unplug electrode from HT lead

Observation:

Thoroughly check the electrode and lead for signs of damage, cracked ceramic insulation, good general condition and cleanliness. Check the spark gap is 2.5 - 4.5mm
Measure the resistance across the electrode, expect continuity / zero resistance.
Refit electrode after test.
Also check the electrode is straight and the correct distance from the burner, if in doubt measure the gap as shown. It should be 7-9mm