Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
CH Demand
Boiler on/off switch ON
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow the ignition sequence to commence.
During the sparking stage of the ignition cycle measure the voltage across the black and blue leads on the gas valve.
Expected voltage should be greater than 150 Volts DC.