Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure Mains Voltage across the Live (L) and the Neutral (N) connections on the 12 way Terminal Block.
If the boiler has an EMC filter (1) then voltage should be measured across the Live and Neutral connections on the input side of the filter.