Set Appliance State:

Mains Power Off
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

If boiler lights allow it to operate until burner shuts off early.
Measure the voltage between the yellow wire marked "NO" at the plug for the air pressure switch (RHS, refer to pictures) to a suitable earth point.
Is mains voltage still present?