Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Voltage Set meter to measure AC Volts
Control Thermostat in high position
High/Low Switch in High position
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow the Boiler to purge itself and the Burner to ignite.
Measure the voltage across connection 1 (Brown wire) and connection 2 (Blue wire) on the connector identified as GV2 on the Interconnection Board.