Set Appliance State:

Mains Power Off
Set Multimeter to AC Voltage Set meter to measure AC Volts
CH Demand
On/Off Switch On.
Gas On
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Allow the Burner to ignite and establish.
Turn off the gas supply and allow the Boiler to Lockout.
Measure Mains Voltage across connection 2 (Red/Black wire) and connection 3 (Blue wire) on the PCB.