Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to DC Volts Set meter to measure DC Volts
Gain access to PCB (use Insulation Mat as required)
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Boiler On/Off switch On.
Reset lockout if necessary.
Measure voltage across terminals 1 (+ve probe) and 8 (-ve probe)
on the low voltage terminal strip marked ST18 on the PCB.