Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to Resistance Set meter to measure resistance
Remove the burner assembly from the boiler

Measurement:

Inspect the spark electrode for general condition.
Make sure the gap to the burner is 10mm (+/- 1mm) and the gap between the probes is 4mm (+/- 0.5mm).
Check for continuity (zero resistance) between the ends of the ignition electrode.