Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Gain access to gas valve connections
Thermostat set to Max
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Observation:

Measure voltage across the terminals of the main gas solenoid
(red and blue wires) to the earth connection.
Test 1:
Measure the voltage across the live (red lead) and the Earth terminal on the main connector block at the front of the control box.
Test 2:
Measure the voltage across the neutral (blue lead) and the Earth terminal on the main connector block at the front of the control box.