Set Appliance State:

Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
Isolate Mains Power to appliance as per TOPs P4
Gain access to PCB
Use insulation mat where necessary
External controls calling for heat
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Measure the voltage across the boiler control thermostat output terminal (yellow wire that runs from the thermostat to the PCB) and the neutral (marked N) on the main connector block.
Expected voltage 230 volts AC (mains voltage).