Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
CH Demand
WARNING! Mains voltage is expected during test, follow TOPs P4 live testing procedure
Mains Power On

Measurement:

Reset boiler as necessary.
Measure voltage between mains N and Pump Live connection (yellow wire) at the terminal block.
Mains voltage expected.
Note:
The pump being correctly wired into the boiler is essential to correct diagnosis for this test.