Set Appliance State:

Gas Off
Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to DC Volts Set meter to measure DC Volts
CH Demand
Main On/Off Control in the On position
CH Temperature Control to Maximum
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

If a fault code is displayed press boiler 'Reset' button.
Measure DC Voltage across bottom/right hand connection (+ve) on the small 3 pin orange plug to a suitable earth point.
Voltage should be approximately 1V to 3.5V DC.