Set Appliance State:

Mains Power Off
Set Multimeter to DC Volts Set meter to measure DC Volts
CH Demand
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Apply a demand and allow boiler to commence ignition sequence.
Measure the voltage at the gas valve connection across the red and blue wires.
Expect initially 22vdc, dropping to 13vdc