Set Appliance State:

Isolate Mains Power to appliance as per TOPs P4
Set Multimeter to AC Volts Set meter to measure AC Volts
Gain access to PCB (use Insulation Mat as required)
CH demand OFF
Gas On
WARNING! - Mains voltage is expected during test follow
TOPs P4 live testing procedure
Mains Power On

Measurement:

Test1:
With no demand measure the voltage to earth at pin-1 (Blue wire) of connector X21,
Expect approximately 10V AC.
Test2:
CH demand ON
Allow the boiler to attempt to light.
Measure the voltage at Pin-1 again, as the flame lights does the voltage change to approx. 5V AC?